THz Spectroscopy of the a1Δg State of O18O and 18O_2.

Physics

Scientific paper

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Microwave (Rotational)

Scientific paper

Submillimeter-wave rotational spectra of O18O and 18O_2 in the a1Δg state have been detected in a new static discharge cell useful for studying rare isotopologues of transient molecules. Rotational transition frequencies of both species have been measured through 1.6 THz, to better than 1 part in 107, allowing precise determination of molecular constants. The first measurements with our static discharge cell provide a check on the isotopic predictions in the a1Δg state.

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