Line-by-line radiative excitation model for the non-equilibrium atmosphere - Application to CO2 15-microns emission

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Atmospheric Models, Carbon Dioxide, Infrared Radiation, Molecular Excitation, Radiative Transfer, Emission Spectra, Thermodynamic Equilibrium

Scientific paper

A new line-by-line algorithm for radiative excitation in infrared bands in a nonlocal thermodynamic equilibrium planetary atmosphere is described. A predictive model for the terrestrial CO2 15-microns emission that incorporates this generic algorithm is developed. The model is validated by comparing its results with emission spectra obtained in a limb-scanning rocket experiment.

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