Millimeter and submillimeter wave spectrum of HCNH(+)

Physics – Chemical Physics

Scientific paper

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Cyano Compounds, Infrared Spectra, Interstellar Chemistry, Microwave Spectra, Molecular Ions, Hydrocarbons, Millimeter Waves, Molecular Rotation

Scientific paper

The molecule HNC is much less stable than its isomer HCN under laboratory conditions. However, it has been detected in several interstellar sources with an abundance comparable to that of HCN. It is pointed out that this phenomenon is a strong support for a production mechanism involving dissociative recombination of the protonated molecule HCNH(+). The present paper is concerned with the observation of three rotational transitions which have been ascribed with high confidence to HCNH(+), after several tests. The three measured transitions are given in a table. The frequencies have been used as a basis for the derivation of the rotational and centrifugal distorsion constants.

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