Rototranslational absorption spectra of H2-H2 pairs in the far infrared

Details Rototranslational absorption spectra of H2-H2 pairs in the far infrared Rototranslational absorption spectra of H2-H2 pairs in the far infrared

Mar 1989

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1989phrva..39.2434m&link_type=abstract

Physical Review A - General Physics, 3rd Series (ISSN 0556-2791), vol. 39, March 1, 1989, p. 2434-2448. Research supported by NA

Physics

General Physics

38

Absorption Spectra, Dipole Moments, Far Infrared Radiation, Hydrogen, Molecular Interactions, Electron States, Ortho Hydrogen, Para Hydrogen

Scientific paper

On the basis of ab initio induced dipole components and a well-tested isotropic potential, the collision-induced absorption rototranslational profiles of hydrogen have been determined using an exact wave-mechanical theory. The main induction mechanisms, particularly the quadrupole-induced 0223,2023 components, are found to be consistent with observations. It is demonstrated that the present theory can be used to predict spectra at temperatures where no measurements exist, as is needed for the modeling of planetary and stellar atmospheres.

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