Frank-Condon factors and r-centroids for the A1Σ+-X1Σ+ and B3Π(0+)-X1Σ+ band system of 63Cu1H and 63Cu2H.

Details Frank-Condon factors and r-centroids for the A1Σ+-X1Σ+ and B3Π(0+)-X1Σ+ band system of 63Cu1H and 63Cu2H. Frank-Condon factors and r-centroids for the A1Σ+-X1Σ+ and B3Π(0+)-X1Σ+ band system of 63Cu1H and 63Cu2H.

Nov 1983

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1983jqsrt..30..439p&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 30, issue 5, pp. 439-447

Physics

1

Molecular Spectra

Scientific paper

The recently reported new RKR potential energy curves for the X1Σ+, A1Σ+, and B3Π(0+) electronic states of 63Cu1H and 63Cu2H are used to calculate Franck-Condon factors and r-centroids for the A-X and B-X band systems for 0 ≤ varcsec ≤ 20, 0 ≤ varcmin ≤ 10 and J = 0, 30, 40. The r-centroid approximation is verified and a physical interpretation of the r-centroid is discussed.

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