Combining VUV lasers with the Time-Sliced Velocity-Mapped Ion Imaging Method for studying the photodissociation of small molecules

Physics

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Scientific paper

We report on an experimental method for the study of extreme ultraviolet (EUV) and vacuum ultraviolet (VUV) photodissociation dynamics of small molecules using time-sliced velocity-mapped ion imaging (TSVMI) detection. The four-wave resonant sum and difference-frequency mixing (FWRSDFM) method is used to provide a relatively intense high repetition rate light source in this region. These two methods are used to study the photodissociation of N2, NO, and CO2 in the energy ranges of 13.0-13.7 and 9.6-10.3 eV. The results indicate that this is a viable method for the study of these molecules in this wavelength region.

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