The green light of the night sky

Physics

Scientific paper

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Molecular Spectra, Nightglow, Oxygen Spectra, Sky Radiation, Upper Atmosphere, Aeronomy, Atmospheric Chemistry, Forbidden Bands, Herzberg Bands, Line Spectra, Molecular Excitation, Reaction Kinetics

Scientific paper

The development of the theory of the 5577 A emission from the upper atmosphere is reviewed. Evidence from both aeronomy and chemical kinetics shows that the Barth mechanism is a much more important source of O(1S) than in the Chapman process. The molecular oxygen state involved is probably c 1 Sigma u - (the upper state of the Herzberg II band system).

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