Manganese solubility control in marine pore waters

Details Manganese solubility control in marine pore waters Manganese solubility control in marine pore waters

Mar 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987gecoa..51..759m&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 51, Issue 3, pp.759-763

Physics

7

Scientific paper

A theoretical study of the system CaCO 3 -MnCO 3 -H 2 O provides evidence that solid solution is limited to three mole fraction ranges corresponding to Mn-calcite, kutnohorite and calcic-rhodochrosite. All these authigenic phases may control the concentration of manganese in suboxic marine pore waters. As a consequence the solubility of manganese cannot be adequately described by a single thermodynamic equilibrium constant.

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