Quantum width and shift of Ar-perturbed K spectral lines in non-impact regime based on a pseudo-potential for the Na/Ar 3s S state

Physics

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Potential Energy Surfaces For Collisions, Line And Band Widths, Shapes, And Shifts

Scientific paper

The equations for a general quantum-mechanical theory for the perturbation shift and broadening of spectral lines in the non-impact regime have been numerically solved for a pseudo-potential of the Na/Ar system in the 3s S state. Spectral line shapes have been shown for low and high pressures (P). The variation with P of the linewidths for the non-impact regime and for the impact approximation is depicted in the range P=0.5-20 torr.

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