Recombination of electrons with NH4/+/-/NH3/n-series ions

Details Recombination of electrons with NH4/+/-/NH3/n-series ions Recombination of electrons with NH4/+/-/NH3/n-series ions

Sep 1976

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1976phrva..14..984h&link_type=abstract

Physical Review A - General Physics, 3rd Series, vol. 14, Sept. 1976, p. 984-989.

Physics

General Physics

24

Ammonia, Electron Recombination, Molecular Ions, Recombination Coefficient, Afterglows, Atmospheric Chemistry, Electron Energy, Mass Spectroscopy, Plasma Diagnostics

Scientific paper

The paper examines the recombination of electrons with ammonium-series cluster ions, NH4(+)-(NH3)n, for two reasons: (1) NH4(+) may be a significant ion in the lower atmospheres of the earth and the outer planets, and (2) to investigate the weak temperature dependence of the cluster ion's recombination coefficient. A microwave afterglow mass spectrometer was used to determine the recombination coefficients for the first five members of the ammonium series, (18+) through (86+), at temperatures between 200 and 410 K. The electron temperature dependence of the recombination coefficient was determined for (35+) and (52+), the n = 1 and 2 cluster ions, over the temperature range 300-3000 K.

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