Improved line parameters for ozone bands in the 10-micron spectral region

Physics – Optics

Scientific paper

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Infrared Spectra, Line Spectra, Oxygen Isotopes, Oxygen Spectra, Ozone, Spectral Bands, Earth Atmosphere, High Resolution, Remote Sensing, Solar Spectra, Stratosphere

Scientific paper

A complete update of spectroscopic line parameters for the 10-micron bands of ozone is reported. The listing contains calculated positions, intensities, lower state energies, and air- and self-broadened halfwidths of more than 53,000 lines. The results have been generated using improved spectroscopic parameters obtained in a number of recent high resolution laboratory studies. A total of eighteen bands of (O-16)3 (sixteen hot bands plus the nu(1) and nu(3) fundamentals) are included along with the nu(1) and nu(3) fundamentals of both (O-16)(O-16)(O-18) and (O-16)(O-18)(O-16). As shown by comparisons of line-by-line simulations with 0.003/cm resolution balloon-borne stratospheric solar spectra, the new parameters greatly improve the accuracy of atmospheric calculations in the 10-micron region, especially for the isotopic (O-16)(O-16)(O-18) and (O-16)(O-18)(O-16) lines.

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