Physics
Scientific paper
Jun 2000
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2000aipc..519..158s&link_type=abstract
STATISTICAL PHYSICS: Third Tohwa University International Conference. AIP Conference Proceedings, Volume 519, pp. 158-163 (2000
Physics
Constant-Composition Solid-Solid Phase Transformations: Polymorphic, Massive, And Order-Disorder
Scientific paper
The polymer chain dynamics during polymerization process has been investigated by means of time-resolved dynamic light scattering (TRDLS) for linear (polystyrene; St) and branched polymer chains (polydivinylbenzene; DVB). Light scattering intensity and time-intensity correlation function (ICF) were obtained every 30 sec during bulk polymerization of St and DVB homopolymers. In the case of DVB, the ICF exhibited a power law behavior exclusively at the gelation point. On the other hand, polymerization of St resulted in formation of vitrified linear polystyrene. It was found that the TRDLS was able to detect the gelation threshold of the DVB system and vitrification of St. .
Norisuye T.
Ozeki S.
Shibayama Mitsuru
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