Physics
Scientific paper
Feb 1974
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1974rspsa.336..495b&link_type=abstract
Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, Volume 336, Issue 1607, pp. 495-505
Physics
8
Scientific paper
The rate constants for the production of vibrationally excited oxygen in the reactions O + ClO2 -> O2(\upsilon ' '<= 15) + ClO O + ClO -> O2(\upsilon ' '<= 14) + Cl are approximately equal for all values of \upsilon ' '<= 13. The oxygen initially receives 45 ± 10% of the heat of reaction in the form of vibrational energy. Extinction coefficients have been measured for several bands of the C-X, D-X and E-X systems of ClO2 in the vacuum ultraviolet. Five new systems are reported between 141 and 128 nm. Two of these, F-X and J-X, and the C-X system form a Rydberg series for an ionization potential of 10.36 eV.
Basco N.
Morse R. D.
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