Temperature dependent UV absorption spectra of carbonyl chloro-fluoride

Details Temperature dependent UV absorption spectra of carbonyl chloro-fluoride Temperature dependent UV absorption spectra of carbonyl chloro-fluoride

Apr 1993

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1993georl..20..707n&link_type=abstract

Geophysical Research Letters (ISSN 0094-8276), vol. 20, no. 8, p. 707-710.

Physics

2

Absorption Cross Sections, Absorption Spectra, Carbonyl Compounds, Photodissociation, Ultraviolet Absorption, Atmospheric Chemistry, Chlorofluorocarbons, Temperature Effects, Ultraviolet Spectroscopy

Scientific paper

The absorption cross-sections of COCIF have been measured in the wavelength range 200-260 nm at temperatures ranging from 298 to 223 K with a spectral resolution of 0.05 nm using diode array spectroscopy. The absorption cross-sections were used to calculate photodissociation rate constants at different solar zenith angles as a function of altitude. Temperature effects of the photodissociation rate constants are discussed.

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