X-ray transition energies-new comprehensive evaluation

Physics

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Multiphoton Ionization And Excitation To Highly Excited States, Calculations And Mathematical Techniques In Atomic And Molecular Physics, Electron Correlation Calculations For Atoms And Molecules

Scientific paper

In this brief report we describe some of the background for our continuing efforts toward a new comprehensive database for x-ray transitions, and indicate the present status of this effort, one that is still a work in progress. In contrast to previous, entirely empirical compilations, ours uses advanced theoretical calculations combined with a sparse network of accurate experimental measurements. The theoretical results closely reproduce high quality experimental data, where they are available, for atoms from Z=22 to Z=90. This suggests that the theoretical estimates are potentially useful in cases where adequate experimental data are absent. Above and below this range, problems emerge which need further examination both theoretically and experimentally.

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