Infrared spectroscopy of homogeneously nucleated hydrazine aerosols - Disordered and crystalline phases

Physics

Scientific paper

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Aerosols, Crystallinity, Hydrazines, Infrared Spectroscopy, Mie Scattering, Planetary Atmospheres, Fourier Transformation, Helium, Order-Disorder Transformations, Planets, Outer Planets, Gas Planets, Atmosphere, Infrared, Wavelengths, Spectroscopy, Aerosols, Hydrazine, Crystalline, Phases, Absorption, Laboratory Studies, Spectra, Scattering, Particles, Size, Distribution, Intensity, Density, Temperature, Crystals, Condensation, Procedure, Refractive Index, Experiments

Scientific paper

It is shown that aerosols generated at low temperatures and high condensation rate spontaneously form in a highly crystalline state. The resonant absorption bands in the IR spectra of these highly crystalline particles are much sharper than any reported previously in the bulk, and reveal details in the N-H vibrational bands that have not been previously observed. A disordered phase is also observed at somewhat higher temperatures. These results are consistent with this being a supercooled liquid. The fact that the spectra associated with these two aerosol phases are quite different is important to any future attempts at detecting hydrazine aerosols in planetary atmospheres by remote sensing techniques.

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