An ab initio study of dissociative electron attachment to NaHCO3 and NaCO3, and the role of these reactions in the formation of sudden sodium layers

Details An ab initio study of dissociative electron attachment to NaHCO3 and NaCO3, and the role of these reactions in the formation of sudden sodium layers An ab initio study of dissociative electron attachment to NaHCO3 and NaCO3, and the role of these reactions in the formation of sudden sodium layers

Jan 1993

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1993georl..20...21r&link_type=abstract

Geophysical Research Letters (ISSN 0094-8276), vol. 20, no. 1, p. 21-24.

Physics

15

Atmospheric Chemistry, Electron Attachment, Sodium Carbonates, Upper Atmosphere, Hot Electrons, Reaction Kinetics, Recombination Reactions

Scientific paper

Ab initio calculations are used to estimate reaction enthalpies for
NaHCO3 and NaCO3. NaHCO3 is shown to be relatively stable above the
mesopause. This property, together with its rather small threshold for
dissociative electron attachment, makes NaHCO3 a possible source of
sudden sodium layers in the upper atmosphere under certain conditions.

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