Theory of time-dependent intense-field collisional resonance fluorescence

Physics – General Physics

Scientific paper

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Approximation, Atomic Collisions, Laser Outputs, Pulsed Lasers, Resonance Fluorescence, Spectral Energy Distribution, Adiabatic Equations, Radiative Transfer, Spectral Correlation, Time Dependence, Zeeman Effect

Scientific paper

The time-dependent theory of Courtens and Szoke (1977) is generalized using the approach of Burnett et al. (1982) to derive time-dependent spectral intensities of resonance fluorescence from atoms driven by a pulsed laser in the presence of collisions. These results are valid both for laser detunings inside and outside the usual impact region of the spectrum, including Zeeman degeneracy effects. This theory is applied to a simple but important example (J = 0 to J = 1) to obtain quantitative predictions for the observable scattered-light spectrum which can be directly compared with recent experiments.

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