Geometrical factors in enhanced photoyield from small metal particles

Physics

Scientific paper

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Relaxation Times And Mean Free Paths, Surface Double Layers, Schottky Barriers, And Work Functions

Scientific paper

A model in which photoexcited electrons in small metal particles are scattered elastically from the boundaries and travel inelastically within is included in a free-electron theory which successfully explains the enhanced photoelectric quantum yield of these systems relative to macroscopic metal surfaces. Application of the theory to the Ag-O-Cs photoemitter where elastic scattering dominates, and Ag aerosols where optical thickness and energy threshold differences between particles of different diameters dominate, gives good results with experiment.

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