Formation of nitric acid hydrates - A chemical equilibrium approach

Details Formation of nitric acid hydrates - A chemical equilibrium approach Formation of nitric acid hydrates - A chemical equilibrium approach

Aug 1990

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1990georl..17.1291s&link_type=abstract

Geophysical Research Letters (ISSN 0094-8276), vol. 17, Aug. 1990, p. 1291-1294.

Physics

9

Atmospheric Chemistry, Chemical Equilibrium, Hydrates, Nitric Acid, Calorimeters, Enthalpy, Entropy, Polar Regions, Stratosphere

Scientific paper

Published data are used to calculate equilibrium constants for reactions of the formation of nitric acid hydrates over the temperature range 190 to 205 K. Standard enthalpies of formation and standard entropies are calculated for the tri- and mono-hydrates. These are shown to be in reasonable agreement with earlier calorimetric measurements. The formation of nitric acid trihydrate in the polar stratosphere is discussed in terms of these equilibrium constants.

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