A symmetry adapted approach to vibrational excitations in atomic clusters

Physics – Chemical Physics

Scientific paper

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8 pages with 2 tables, invited talk at `Atomic Nuclei & Metallic Clusters: Finite Many-Fermion Systems', Prague, Czech Republi

Scientific paper

10.1023/A:1021482831895

An algebraic method especially suited to describe strongly anharmonic vibrational spectra in molecules may be an appropriate framework to study vibrational spectra of Na$^+_n$ clusters, where nearly flat potential energy surfaces and the appearance of close lying isomers have been reported. As an illustration we describe the model and apply it to the Be$_4$, H$_3^+$, Be$_3$ and Na$_3^+$ clusters.

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