Physics
Scientific paper
Feb 1954
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1954rspsa.221..517c&link_type=abstract
Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, Volume 221, Issue 1147, pp. 517-534
Physics
2
Scientific paper
The vapour pressures of condensed liquid mixtures of argon and oxygen of known composition have been measured by means of a differential mercury manometer with reference to the vapour pressure of pure argon. From these results it is possible to determine the bubble-point curves of the system over a series of fixed temperatures. In the second part of the experimental work the composition differences between liquid and vapour phases in equilibrium were determined at three constant temperatures by a static method. The results have been extensively checked and smoothed by graphical and analytical methods. A test for thermodynamic consistency has been applied, and it is believed that the results are consistent within the accuracy of the assessment. The final data are presented in tabular form for rounded-off values of composition and temperature. Constants and formulae have been worked out which enable values to be calculated for any pressure, temperature or composition.
Clark Michael A.
Din F.
Robb J.
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