Fitting law for the density shift of Q(J) transitions of H2 in H2-X (X: H2, He, N2) mixtures.

Details Fitting law for the density shift of Q(J) transitions of H2 in H2-X (X: H2, He, N2) mixtures. Fitting law for the density shift of Q(J) transitions of H2 in H2-X (X: H2, He, N2) mixtures.

Oct 1998

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1998jqsrt..60..585m&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 60, issue 4, pp. 585-591

Physics

2

Molecular Hydrogen: Molecular Processes, Molecular Hydrogen: Line Broadening

Scientific paper

A variety of fitting laws have been developed for the purpose of modelling broadening effects in collisional processes, but only a few have been proposed for modelling collision-induced lineshifts in molecules. The authors analysed accurate stimulated Raman data obtained in several H2-X mixtures (X: H2, He and N2). For the first time, the authors show that an empirical law provides a very good representation of collisional lineshift coefficients in the range 300-1200 K and for J quantum number up to 9.

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