Physics
Scientific paper
Nov 1978
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1978sci...202..751s&link_type=abstract
Science, vol. 202, Nov. 17, 1978, p. 751-753.
Physics
2
Emission Spectra, Metastable State, Optical Transition, Oxygen Spectra, Radiative Recombination, Afterglows, Electron Transitions, Ground State, Helium, Microwave Transmission, Oxygen Atoms, Radio Frequency Discharge, Reaction Kinetics
Scientific paper
Recombination of ground-state oxygen atoms populates six different bound electronic states of molecular oxygen. Of the six optical transitions expected between the three upper states at 4 to 4.5 electron volts and the two lowest states, five have been observed in the afterglow of a conventional helium-oxygen microwave discharge in both (O-16)2 and (O-18)2, three of them for the first time in gas-phase spectra. Generation of these emissions from oxygen atoms in a system free of molecular oxygen establishes that atom recombination is the production mechanism.
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