A Hybrid Algebraic/Schrödinger Approach to the 2D Franck-Condon Problem

Details A Hybrid Algebraic/Schrödinger Approach to the 2D Franck-Condon Problem A Hybrid Algebraic/Schrödinger Approach to the 2D Franck-Condon Problem

2000-05-15

arxiv.org/abs/physics/0005036v1

Physics

Chemical Physics

19 pages, 4 figures

Scientific paper

We use recent results regarding the geometry of the U(3) bosonic algebraic
model to motivate a hybrid algebraic-Schr\"odinger approach to the 2D
Franck-Condon problem analogous to 1D approaches. This approach allows one to
analyze bent to linear Franck-Condon transitions of triatomic molecules as well
as clarifies the angular momentum dependance of the Franck-Condon intensities.

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