Relativistic semiclassical atomic transition rates

Physics

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Atomic Structure, Conservation Equations, Dirac Equation, Electron Transitions, Energy Levels, Plasmas (Physics), Relativistic Effects, Wentzel-Kramer-Brillouin Method, Predictions, Rates (Per Time), Wave Functions

Scientific paper

This paper gives a new semiclassical (WKB) solution of the one-electron Dirac equation for electrons in a spherically symmetric atomic potential. The two-component wave-function has several favorable formal properties: it exactly satisfies a relativistic probability conservation equation and exactly reduces to the nonrelativistic semiclassical solution in every detail (including the Langer modification). The solution gives satisfactory predictions of energy-levels, orbit radii and radiative line-strengths.

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