Electronic Spectroscopy of the 6p ← 6s Transition in Au-Ne

Physics

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Electronic

Scientific paper

Electronic spectra of the Au-Ne complex have been recorded for the first time in the vicinity of the atomic Au 6p ← 6s transition. A structured spectrum was observed near the Au ^2P3/2 ← ^2S1/2 transition, however, the complex spectrum expected near the Au ^2P1/2 ← ^2S1/2 transition was not observed. This is rationalized using high level ab intio calculations.
R. J. Plowright, A. M. Gardner, C. D. Withers, T. G. Wright, M. D. Morse and W. H. Breckenridge, J. Phys. Chem. A, 114, 3103, (2010)

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