Torsional Excitation in O-H Stretch Overtone Spectra of Ethyl Hydroperoxide Conformers

Physics

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Scientific paper

Photoacoustic spectra at 3-6 quanta of O-H stretch show features
attributed to torsion about the O-O bond and to distinct contributions
from two conformers. Laser-induced fluorescence detection of OH
radicals demonstrates unimolecular dissociation from some vibrationally
and torsionally excited states.

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