The photoionization and dissociative photoionization of H2, HD, and D2

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Deuterium, Gas Ionization, Hydrogen Ions, Ionization Cross Sections, Photoionization, Vibrational Spectra, Gas Dissociation, Interstellar Gas, Molecular Energy Levels, Photodissociation, Planetary Atmospheres, Ultraviolet Radiation, Wave Functions

Scientific paper

The cross sections for photoionization of H2 to the bound and continuum vibrational levels of the 1s sigma g state of H2(+) have been calculated in the range 804-425 A ionizing radiation. The dipole matrix elements have been computed as a function of ejected electron energy and internuclear distance using a simple Coulomb approximation to the final-state scattering wave function. The relative population of the V' levels of H2(+) at 584 A, the ratio of production of H(+) to H2(+) as a function of photon energy, and the total photoionization cross section are in good agreement with experimental measurements.

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