Some Theoretical Considerations about the Origin of the 220 NM Interstellar Hump

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Scientific paper

The density of state (σ and π) of a small graphite-like planar cluster is computed using a tight binding approach. We point out a possible correlation between the presence of surface levels, dependent on the cluster size and localized near the middle of the σ band gap, and the origin of the 220 nm interstellar hump. The influence of sp3 sites — or impurities — randomly distributed throughout the cluster, is also discussed.

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