Probabilities for electronic transitions of molecular systems of high-temperature air components. II - The gamma and beta systems of NO and the /4+/ system of CO

Details Probabilities for electronic transitions of molecular systems of high-temperature air components. II - The gamma and beta systems of NO and the /4+/ system of CO Probabilities for electronic transitions of molecular systems of high-temperature air components. II - The gamma and beta systems of NO and the /4+/ system of CO

Sep 1980

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1980jqsrt..24..219k&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 24, Sept. 1980, p. 219-227.

Computer Science

6

Atmospheric Composition, Carbon Monoxide, Electron Transitions, Molecular Spectra, Nitric Oxide, Transition Probabilities, High Temperature Environments, Molecular Gases, Molecular Relaxation, Spectral Bands, Vibrational Spectra

Scientific paper

Literature results on absolute and relative probabilities for electronic transitions and on lifetimes of electronically excited states in the gamma and beta systems of the NO molecule and in the (4+) system of the CO molecule are critically analyzed. The results of previous studies to establish the dependence of the electronic transition strength on the r-centroid for these molecular systems are shown to be inadequate. Using a combined analysis of absolute and relative probabilities, new normalized functions are obtained that describe the behaviour of the transition strengths in the spectral ranges occupied by the gamma and beta systems of NO and by the (4+) system of CO.

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