The - inversions in eucryptite and spodumene

Details The - inversions in eucryptite and spodumene The - inversions in eucryptite and spodumene

Dec 1958

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1958gecoa..15..213i&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 15, Issue 3, pp.213-217

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Scientific paper

Reversible hydrothermal experiments have allowed the unequivocal determination of the p - t dependence of the LiAlSiO 4(willemite) /ag LiAlSiO 4(high-quartz) reaction. This constitutes one of the few reconstructive phase changes so studied. The revised - inversion temperature at atmospheric pressure is set at 848 ± 5°C and the enthalpy of inversion is calculated as 3750 cal/mole LiAlSiO 4 . It was found impossible to study the - spodumene inversion, since in no case could -spodumene be synthesized from its own composition at pressures up to 4000 atm. The assemblage -eucryptite + petalite appeared consistently instead.

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