Boron and Lithium Isotopic Composition in Chondrules

Astronomy and Astrophysics – Astrophysics

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Scientific paper

Recent ion microprobe investigations have revealed large boron isotope variations (d11B values ranging between -50 and +40) in some chondrules from the Semarkona, Hedjaz and Allende chondrites [1].Up to 60 variations can be found in a single chondrule. The d11B values and the B/Si ratios (varying between 510-6 and 410-4) were found to be positively correlated. Since boron in the Universe cannot orginate from thermonuclear reactions in stars these isotopic variations are interpreted as the result of a mixing in the protosolar nebula between two different sources of spallogenic boron : (1) an interstellar source where boron results from reactions between high energy galactic cosmic rays (protons and alpha particles; >100 MeV) and interstellar nuclei yielding low B/Si and 11B/10B ratios (d11B -400) and (2) a molecular cloud source where boron results from reactions between low energy particles (C and O; <30 MeV) and low temperature H2 and He (as recently observed in Orion [3]) yielding high B/Si and 11B/10B ratios (d11B +110). The reactions producing 11B-rich boron would have occurred in the dense molecular cloud that predates the formation of the solar nebula. Detailed astrophysical calculations [4] are in agreement with this geochemical model. According to this model--and provided that the degree of isotopic homogenisation within the same chondrule is the same for Li and B--it can be shown that d7Li() and d11B() should be related by a 1:1 linear correlation with low d7Li values associated with high d11B values. Therefore, in order to test one of the clearest predictions of our interpretation, new ion microprobe determinations of Li-Be-B and major elements (Na, K, Ca, Mg, Si) concentrations and of the 11B/10B and 7Li/6Li isotopic ratios in meteoritic chondrules were performed. Considering all our measured chondrules, the Li/B ratio varies by 2 order of magnitude indicating that the two chemical elements were fractionated during the formation of chondrules. Therefore, the 7Li/6Li isotopic ratio was measured only in chondrules showing a homogeneous Li/B ratio and a value close to its spallogenic theoretical ratio (Li/B 1). References: [1] Chaussidon and Robert (1995) Nature, 374, 337-339. [2] Meneguzzi et al. (1971) Astron. Astrophys., 15, 337-359. [3] Bloemen et al. (1994) Astron. Astrophys., 281, L5-L8. [4] Ramaty et al., Astrophys. J., submitted.

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