Water vapor continuous absorption in various mixtures: possible role of weakly bound complexes.

Details Water vapor continuous absorption in various mixtures: possible role of weakly bound complexes. Water vapor continuous absorption in various mixtures: possible role of weakly bound complexes.

Jan 2000

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2000jqsrt..64...25v&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 64, issue 1, pp. 25-40

Computer Science

15

Infrared Absorption: Water Vapor

Scientific paper

The model is suggested to describe the temperature dependence of mm-wave and infrared continua absorption in terms of absorption by weakly bound binary complexes. Present approach is applicable to a mixture of water vapor with various gases. It is shown that accurate consideration of mass action law for (H2O)2 dimers and H2O-N2, H2O-CO2, and H2O-Ar complexes allows to reproduce temperature dependencies of continua absorption measured at different wavelengths in mixtures containing various amount of water vapor. The model can be generalized to rigorously account for details of potential energy and dipole surfaces relevant to water-water and water-foreign gas interactions.

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