Computer Science
Scientific paper
May 1990
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1990nascp3077...78s&link_type=abstract
In NASA, Goddard Space Flight Center, First International Conference on Laboratory Research for Planetary Atmospheres p 78-84 (S
Computer Science
Bonding, Microwave Spectra, Planetary Atmospheres, Rotational Spectra, Splitting, Van Der Waals Forces, Dimers, Fabry-Perot Spectrometers, Microwave Spectrometers, Trimers
Scientific paper
The Fourier-transform Fabry-Perot pulsed-molecular-beam microwave spectrometer at NIST was used to study the microwave spectra of a number of molecular dimers and trimers that may be present in planetary atmospheres. The weak van der Waals bonds associated with these species usually give rise to rotational-tunneling splittings in the microwave spectra. The microwave spectrum of the water dimer species was used to illustrate the complications that can arise in the study of the rotational spectra of these loosely bound species. In addition to the water dimer species, the microwave spectra of the following hydrogen-bonded and van der Waals complexes were studied: (CO2)2-H2O, CO2-(H2O)2, CO2-H2S, N2-H2O, CO-H2O, SO2-H2O, and O3-H2O.
Lovas Francis J.
Suenram Richard D.
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