The (j, k) = (3, 3) inversion line of NH3 - A possible interstellar chronometer

Astronomy and Astrophysics – Astronomy

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Ammonia, Chemical Evolution, Interstellar Matter, Molecular Clouds, Abundance, Dark Matter, Density Distribution, Interstellar Masers, Molecular Collisions

Scientific paper

Calculations show that ortho-H2 and para-H2 exhibit different propensity rules in collisions with NH3. In particular, para-H2 tends to preferentially excite the upper (3 3 - ) component of the (j, k) = (3, 3) inversion doublet. Assuming collisional excitation, the existence of a maser in this transition within a molecular cloud implies an upper limit to the ratio of densities, n(o-H2)/n(p-H2). As this density ratio evolves (chemically) with time, to its upper limit there corresponds a lower limit to the age of the cloud. Calculations of the time-dependence of n(o-H2)/n(p-H2) enable this interstellar chronometer to be calibrated.

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