Rotational spectra of carbon 13 and vibrationally excited SiC

Astronomy and Astrophysics – Astronomy

Scientific paper

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Carbon Isotopes, Radio Sources (Astronomy), Rotational Spectra, Silicon Carbides, Stellar Envelopes, Hyperfine Structure, Line Spectra, Molecular Excitation, Vibrational Spectra

Scientific paper

The millimeter-wave rotational spectra of SiC-13 and vibrationally excited SiC in the X3Pi state have been measured between 149 and 291 GHz in a laboratory discharge through SiH4 and CO. Hyperfine splittings in the SiC-13 spectra are well resolved, allowing accurate determination of all four hyperfine constants. The fine-structure, rotational, centrifugal distortion, and lambda-doubling constants for SiC-13 and v = 1 SiC have been determined to sufficient accuracy that the entire rotational spectrum can be calculated into the far-IR.

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