Mathematics – Logic
Scientific paper
Jul 2003
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2003phdt.........3s&link_type=abstract
PhD Thesis University of Karlsruhe, Germany
Mathematics
Logic
4
K-T Boundary, Maastrichtian, Danian, Chicxulub Impact, Northeastern Mexico, Brazos, Texas, Alabama, Yucatan, Impact Ejecta, Target Lithologies, Spherules, Microtektites, Microkrystites, Liquid Immiscibility, Sequence Stratigraphy, Sea-Level Changes, Paleoclimate, Mass Extinctions
Scientific paper
The Cretaceous-Paleogene (K-P) transition is characterized by a period of mass extinctions, the Chicxulub impact event, sea-level changes, and considerable climate changes (e.g., cooling). The Gulf of Mexico region is a key area for addressing these issues, specifically because of the proximity to the large Chicxulub impact structure in southern Mexico, and because of its shallow shelf areas throughout the Maastrichtian to Danian period. This study presents the results of a multidisciplinary investigation of Chicxulub impact ejecta and marine sediments from the K-P transition in the western Gulf of Mexico. Sedimentological, mineralogical, and geochemical aspects of K-P sections and cores from northeastern Mexico, Texas, and Alabama have been by studied with focus on Chicxulub ejecta, long- or short-term facies change, and sequence stratigraphic setting. CHICXULUB EJECTA: The Chicxulub ejecta (or impact spherule) deposits from northeastern Mexico and Texas revealed an unexpected complex and localized ejecta composition. Fe-Mg-rich chlorite- as well as Si-Al-K-rich glass-spherules are the predominant silicic ejecta components in northeastern Mexico, whereas in Texas, spherules of Mg-rich smectite compositions were encountered. Spherules contain Fe-Ti-K-rich schlieren, Fe-Mg-rich globules, and rare µm-sized metallic and sulfidic Ni-Co-(Ir-?) rich inclusions. This composition provides evidence for a distinct range of target rocks of mafic to intermediate composition, presumably situated in the northwestern sector of the Chicxulub impact structure, in addition to the possibility of contamination by meteoritic material. The absence of spinels and the ubiquitous presence of hematite and goethite points to high oxygen fugacity during the impact process. Besides these silicic phases, the most prominent ejecta component is carbonate.!
Carbonate is found in ejecta deposits as unshocked clasts, accretionary lapilli-like grains, melt globules (often with quenching textures), and as microspar, suggesting that this area received ejecta mainly from shallow, carbonate-rich lithologies at the impact site on the Yucatán carbonate platform. Albeit the ejecta spherules are mostly altered to clay minerals and iron oxides, the microfacies and internal textures of the ejecta particles show a variety of distinct features, including welding and fusing of components and evidence for liquid immiscibility between silicic-silicic and carbonate-silicic melts. No evidence for binary mixing of ejecta phases was found. Therefore, it is assumed that ejecta in northeastern Mexico derived from less energetic parts of the ejecta curtain. The welding features of ejecta particles suggest an initial ground surge-like ejecta-dispersion mode. The specific morphological features and the compositional range of Chicxulub ejecta, as well as the results of petrological and rock magnetic characteristics reveal similarities to Chicxulub ejecta from K-P sections in the Gulf of Mexico area, the Caribbean, the Atlantic, the Pacific, and Northern America (Western Interior). In addition, Mg-rich smectite, K-feldspar, and iron oxide-rich microspherules are characteristic for the K-P boundary clay layer in sections from the Atlantic and Tethyan realm, suggestive of a relationship between the Chicxulub impact event and the basal K-P boundary clay layer. EJECTA DEPOSITS: The Chicxulub ejecta deposits are commonly associated with an event deposit that shows a complex succession of deposition from high-energetic (channelized) debris flows or turbidity currents derived from multiple source areas, followed by a period of decreasing current energy and intermittent periods of reworking. The uppermost parts of these deposits are often bioturbated, pointing to longer periods of deposition, as also sustained by the complex internal subdivision of the K-P event deposits. In northeastern Mexico, Chicxulub ejecta is also locally embedded within latest Maastrichtian marls, though common soft-sediment deformation opposes a clear age assignation of these deposits. However, individual spherule layers in the slumped and in the channelized spherule deposits are of similar petrological, mineralogical, and geochemical composition with no size-sorting and abrasion of ejecta, hence pointing to an origin from a single impact event (Chicxulub) and providing no evidence for extended periods between reworking of individual spherule layers. In the Brazos core from Texas, a m-thick shale interval, almost devoid of micro- and macrofossils and therefore of unclear stratigraphic age, is sandwiched between Chicxulub impact ejecta and the first appearance of Paleocene microfossils, indicating a period (of enhanced reworking?) between these two events. However, no mm-thick ferruginous layer with Ni-rich spinels, smectite spherules, and shocked quartz that defines the K-P boundary in the Global Stratotype Section and Point (GSSP) at El Kef, Tunisia, and elsewhere has been observed in any of the sections and cores studied. Therefore, an unequivocal positioning of the K-P boundary is difficult for the northwestern Gulf of Mexico region. PALEOCLIMATE RECORD: The long-term record of clay mineral species during the K-P transition of northeastern Mexico, Texas, and Alabama shows remarkably localized compositional patterns, indicating local sediment influx from topographically, petrologically, and probably climatically distinct source regions. Chlorite-illite-dominated clay assemblages in northwestern Mexico indicate mafic source rocks, predominance of physical weathering, and cooler climates, probably associated with the uplift of the Sierra Madre Oriental, whereas a smectite-dominated clay assemblage in Texas indicates semiarid-humid climates. In central Alabama, a distinct trend from tropically humid and warm climates to more seasonal and drier climate that already started in the late Maastrichtian was inferred from a prominent change of a kaolinite- to a smectite-dominated clay mineral assemblage. Hence, no unique climate conditions and distinct climate trends can be inferred for the northwestern Gulf of Mexico area from the data provided by this study. SEQUENCE STRATIGRAPHY: The sequence stratigraphic setting of the Maastrichtian to Danian strata in northeastern Mexico, Texas, and Alabama is also quite complex. The deep-water marls in northeastern Mexico were not amenable to a clear sequence stratigraphic subdivision, though the similar mineralogical (and geochemical) composition of the Maastrichtian to Danian marls provided no evidence for a distinct major facies change during this interval. In Texas, no facies change was observed for the (highstand) shale interval that includes the event bed, though a gradual sea-level lowering took place upon the appearance of the earliest Paleocene microfossils. A sequence boundary is present in the earliest Danian and overlain by transgressive systems tract. In central Alabama, a pronounced sea-level shallowing was recognized during a highstand systems tract in the late Maastrichtian, topped by a sequence boundary and subsequent (strongly) rising sea level throughout the latest Maastrichtian and the early Danian. Rapid and intense water-depth fluctuations are inferred from middle Danian carbonate-rich strata concomitant to a change from a mixed siliciclastic-carbonate depositional system to a more stable carbonate platform in central Alabama during this period. In summary, no universal pattern of facies and related sea-level changes was obtained from the northwestern Gulf of Mexico area, and particularly, no evidence for adverse an- or dysoxic sedimentary conditions were observed for the Maastrichtian to Danian interval governed by this study.
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