Solid organic residues produced by irradiation of hydrocarbon-containing H2O and H2O/NH3 ices - Infrared spectroscopy and astronomical implications

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Ammonia, Comet Nuclei, Interstellar Matter, Irradiation, Organic Compounds, Water, Absorption Spectra, Hydrocarbons, Ice, Infrared Spectra, Satellites, Spectrum Analysis, Planets, Organic Material, Residue, Irradiation, Hydrocarbons, Ammonia, Water, Ice, Infrared, Wavelengths, Spectroscopy, Formation, Diagrams, Origin, Laboratory Studies, Methane, Clathrates, Procedure, Experiments, Aldehydes, Spectra, Comparisons

Scientific paper

Plasma-discharge irradiations were conducted for the methane clathrate expected in outer solar system satellites and cometary nuclei; also irradiated were ices prepared from other combinations of H2O with CH4, C2H6, or C2H2. Upon evaporation of the yellowish-to-tan irradiated ices, it is found that a colored solid film adheres to the walls of the reaction vessel at room temperature. These organic films are found to exhibit IR band identifiable with alkane, aldehide, alcohol, and perhaps alkene, as well as substituted aromatic functional groups. These spectra are compared with previous studies of UV- or photon-irradiated nonclathrated hydrocarbon-containing ices.

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