Constraints on Martian Differentiation Processes from Rb-Sr and Sm-Nd Isotopic Analyses of the Basaltic Shergottite QUE 94201

Mathematics – Logic

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Mars (Planet), Mars Surface, Planetary Geology, Isotopes, Ion Probes, Rubidium 86, Samarium Isotopes, Rubidium Isotopes, Neodymium Isotopes, Shergottites, Rocks, Minerals, Decoupling, Crystallization, Crusts, Basalt

Scientific paper

Isotopic analyses of mineral, leachate, and whole rock fractions from the Martian shergottite meteorite QUE 94201 yield Rb-Sr and Sm-Nd crystallization ages of 327 +/- 12 and 327 +/- 19 Ma, respectively. These ages are concordant, although the isochrons are defined by different fractions within the meteorite. Comparison of isotope dilution Sm and Nd data for the various QUE 94201 fractions with in situ ion microprobe data for QUE 94201 minerals from the literature demonstrate the presence of a leachable crustal component in the meteorite. This component is likely to have been added to QUE 94201 by secondary alteration processes on Mars, and can affect the isochrons by selectively altering the isotopic systematics of the leachates and some of the mineral fractions. The absence of crustal recycling processes on Mars may preserve the geochemical evidence for early differentiation and the decoupling of the Rb-Sr and Sm-Nd isotopic systems, underscoring one of the fundamental differences between geologic processes on Mars and the Earth.

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