Time-dependent chemistry in dense molecular clouds. IV - Interstellar grain surface reactions inferred from a matrix isolation study

Astronomy and Astrophysics – Astrophysics

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Infrared Spectroscopy, Interstellar Matter, Molecular Clouds, Surface Reactions, Time Dependence, Absorption Spectra, Carbon Dioxide, Carbon Monoxide, Infrared Spectra

Scientific paper

A laboratory investigation of two potentially important grain surface reactions is presented. The reactions considered, CO + O yields CO2 and O2 + O yields O3, are studied with the use of matrix isolation techniques and Fourier transform-infrared spectroscopy. The method is described in a general way and can be applied to modeling various low temperature surface reactions of astrophysical relevance for the production of molecules in dense molecular clouds. It is shown that the reaction CO + O yields CO2 does not take place at low temperatures (10-30 K) because it possesses an activation energy barrier. On the other hand, the reaction O2 + 0 yields O3 proceeds readily. If CO2 is indeed present in interstellar grain mantles, it implies the occurrence of high energy processes, such as ultraviolet photolysis or cosmic-ray processing of these mantles, processes which can be simulated in the laboratory.

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