Measurements of pressure-induced shifts in the 1-0 and 2-0 bands of HF and in the 2-0 bands of HCl-35 and HCl-37

Astronomy and Astrophysics – Astronomy

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Gas Pressure, Hydrochloric Acid, Hydrofluoric Acid, Infrared Spectroscopy, Pressure Effects, Spectral Bands, Astronomical Spectroscopy, Atmospheric Composition, Graphs (Charts), Isotope Effect, Molecular Spectra, Planetary Atmospheres

Scientific paper

Fourier absorption spectra of HCl and HF measured at room temperature and low pressures were found to indicate pressure-induced shifts of the spectral lines at gas pressures of only 10 torr. Self-induced shifts were determined for the HF 2-0 band and for the HCl-35 and HCl-37 2-0 bands, and shift oscillations in the 2-0 bands due to near-resonant dipole-dipole interactions between the two gases were also evaluated. Separate measurements of pressure-induced shifts in the HF 1-0 and 2-0 bands and in both isotopic HCl bands were obtained using argon, neon, nitrogen, and CO2 separately as the perturbing gases.

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