Stratospheric O3 and NO2 observations at the southern polar circle in summer and fall 1988

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Antarctic Regions, Diurnal Variations, Nitrogen Dioxide, Ozone, Spectrometers, Stratosphere, Autumn, Photodissociation, Photolysis, Summer

Scientific paper

A visible spectrometer dedicated to ozone and NO2 monitoring for the next few years has been installed at the French Antarctica base of Dumont d'Urville at 66 deg S, 140 deg E. The first three months of data in Austral summer and fall allow the observation of the NO2 seasonal decay together with its diurnal variation. The data are found to be incompatible with the currently accepted NO(X) photochemistry. A conversion of nitrogen compounds into another storage species is required. The reaction which probably involves N2O5 should be active at temperature as high as -45 C.

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