Semiempirical Calculation of gf Values: sc II (3d+4s)2 - (3d+4s) 4p, a Detialed Example

Details Semiempirical Calculation of gf Values: sc II (3d+4s)2 - (3d+4s) 4p, a Detialed Example Semiempirical Calculation of gf Values: sc II (3d+4s)2 - (3d+4s) 4p, a Detialed Example

May 1973

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1973saosr.351.....k&link_type=abstract

SAO Special Report #351 (1973)

Computer Science

16

Scientific paper

A semiempirical procedure for calculating gf values is developed in detail. A program written by R. D. Cowan is used to produce LS transition arrays and electrostatic and spin-orbit matrices. Transition integrals are evaluated with scaled Thomas- Fermi-Dirac wavefuntions following Warner. Eigenvectors are found through a least-squares procedure that fits computed eigenvalues to observed energy levels, and then the eigenvectors are used to transform the LS transition array to the observed coupling scheme. Throughout the discussion, examples are given for Sc II (3d+4s)2 - (3d+4s) 4p. The final computed gf values are compared to laboratory measurements.

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