The Pure Rotational Spectra of CrS (X^{5}Π_r): Continued Studies of the 3d Transition Metal Sulfides

Details The Pure Rotational Spectra of CrS (X^{5}Π_r): Continued Studies of the 3d Transition Metal Sulfides The Pure Rotational Spectra of CrS (X^{5}Π_r): Continued Studies of the 3d Transition Metal Sulfides

Jun 2009

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009mss..conferh09p&link_type=abstract

"International Symposium On Molecular Spectroscopy, 64th Meeting, Held 22-26 June, 2009 at Ohio State University. http://molspec

Computer Science

Microwave

Scientific paper

The pure rotational spectrum of CrS has been measured in the ground X^{5}Π_r state using gas-phase direct absorption methods in the frequency range of 280-405 GHz. The molecule was created by the reaction of chromium vapor, sublimed in a Broida oven, with hydrogen sulfide gas. All five spin components were observed in eleven rotational transitions, and lambda-doubling splitting were resolved in the Ω = 0, 1 and 2 ladders. The data were fit with a Hund's case(a) Hamiltonian and rotational, spin-orbit, spin-spin, and lambda-doubling constants have been established. A bond length of 2.0781 Å was derived from the data. Using the lambda-doubling parameters, the energy difference between the ground X^{5}Π and excited ^{5}Σ state was estimated to be 1400 cm ^{-1}.

Affiliated with

Also associated with

No associations

Rating

The Pure Rotational Spectra of CrS (X^{5}Π_r): Continued Studies of the 3d Transition Metal Sulfides does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with The Pure Rotational Spectra of CrS (X^{5}Π_r): Continued Studies of the 3d Transition Metal Sulfides, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and The Pure Rotational Spectra of CrS (X^{5}Π_r): Continued Studies of the 3d Transition Metal Sulfides will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-1641959