The A^{2}Π-X^{2}Σ^+ Band System of SrF Revisited

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Recently DeMille et al. proposed using ^{87}SrF and other heavy diatomic molecules to measure nuclear spin-dependent parity violation (NSD-PV). In this scheme the N=0 (+-parity) levels of the X^{2}Σ^+ (v=0) state will be magnetically tuned into near degeneracy with the N=1(- parity) levels. The pairs of nearly degenerate levels are mixed by NSD-PV interactions. The process will be monitored using the optical A^{2}Π-X^{2}Σ^+ transition. Here we report on the analysis of the (1,0) band for ^{88}SrF and the (0,0) band for ^{87}SrF of the A^{2}Π-X^{2}Σ^+ system recorded at near natural linewidth limit. A combined fit of the optical spectra with the previously recorded rf-transitions and pure rotational transitions was performed.
D. DeMille, S.B. Cahn, D. Murphree, D.A. Rahmlow and M.G. Kozlov, Phys. Rev. Lett. 100 023003, 2008.
Y. Azuma, W. J. Childs and G. L. Goodman, T. C. Steimle, J. Chem. Phys. 93 1990 93, 5533.
U. Schültz-Pahlmann, Ch. Ryzlewicz, J. Hoeft,and T. Törring, 93,74 (1982)Chem. Phys. Lett. 93 74, 1982.

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