The Pure Rotational Spectrum of Tis (X^{3}Δ_r) in all Three Spin Components

Details The Pure Rotational Spectrum of Tis (X^{3}Δ_r) in all Three Spin Components The Pure Rotational Spectrum of Tis (X^{3}Δ_r) in all Three Spin Components

Jun 2009

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009mss..confefc11p&link_type=abstract

"International Symposium On Molecular Spectroscopy, 64th Meeting, Held 22-26 June, 2009 at Ohio State University. http://molspec

Computer Science

Microwave

Scientific paper

The pure rotational spectrum of TiS in the X^{3}Δ_r ground state has been measured using millimeter-wave direct absorption techniques. This species was created by the reaction of hydrogen sulfide gas with titanium vapor produced in a Broida oven which was modified to withstand the extreme temperatures required to melt this metal. Eight transitions have been recorded, each consisting of three spin components. No lambda-doubling was observed, as expected for a Δ state. The data were fit with a Hund's case(a) Hamiltonian and spectroscopic constants have been determined. The results from this study, as well as a comparison to past optical data will be presented.

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