The Pure Rotational Spectrum of ZnS (X^{1}Σ^{+})

Details The Pure Rotational Spectrum of ZnS (X^{1}Σ^{+}) The Pure Rotational Spectrum of ZnS (X^{1}Σ^{+})

Jun 2009

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009mss..confefc02z&link_type=abstract

"International Symposium On Molecular Spectroscopy, 64th Meeting, Held 22-26 June, 2009 at Ohio State University. http://molspec

Computer Science

Microwave

Scientific paper

Millimeter-wave direct-absorption techniques have been used to measure the pure rotational spectrum of ZnS (X^{1}Σ^{+}). This work is the first spectroscopic study of ZnS in the gas phase. This molecule was produced by the reaction of zinc vapor and H_2S under DC discharge conditions. Eight rotational transitions were recorded for four stable zinc isotopologues of ZnS in the v = 0 state, and data were also obtained for ^{64}ZnS and ^{66}ZnS in the v = 1 state. The data have been analyzed and spectroscopic constants and equilibrium parameters have been determined. The equilibrium bond length of ZnS was established to be 2.0464 Å, as compared to 1.7047 {Å} for ZnO.

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