Isotopic properties of silicon carbide X grains from the Murchison meteorite in the size range 0.5-1.5 μm

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We report isotopic abundances for C, N, Mg-Al, Si, Ca-Ti, and Fe in 99 presolar silicon carbide grains of type X (84 grains from this work and 15 grains from previous studies) from the Murchison CM2 meteorite, ranging in size from 0.5 to 1.5 μm. Carbon was measured in 41 X grains, N in 37 grains, Mg-Al in 18 grains, Si in 87 grains, Ca-Ti in 25 grains, and Fe in 8 grains. These X grains have 12C/13C ratios between 18 and 6,800, 14N/15N ratios from 13 to 200, ???Si/28Si between -750 and +60 deg, ???Si/28Si from -770 to -10 deg, and 54Fe/56Fe ratios that are compatible with solar within the analytical uncertainties of several 10 percent. Many X grains carry large amounts of radiogenic 26Mg (from the radioactive decay of 26Al, half life ( 7 105 a) and radiogenic 44Ca (from the radioactive decay of 44Ti, half life = 60 a). While all X grains but one have radiogenic 26Mg, only about 20 percent of them have detectable amounts of radiogenic 44Ca. Initial 26Al/27Al ratios of up to 0.36 and initial 44Ti/48Ti ratios of up to 0.56 can be inferred. The isotopic data are compared with those expected from the potential stellar sources of silicon carbide dust. Carbon stars, Wolf-Rayet stars, and novae are ruled out as stellar sources of the X grains. The isotopic compositions of C and Fe and abundances of extinct 44Ti are well explained both by type Ia and type II supernova (SN) models. The same holds for 26Al/27Al ratios except for the highest 26Al/27Al ratios of > 0.2 in some X grains. Silicon agrees qualitatively with SN model predictions but the observed 29Si/30Si ratios in the X grains are in most cases too high, pointing to deficiencies in the current understanding of the production of Si in SN environments. The measured 14N/15N ratios are lower than those expected from SN mixing models. This problem can be overcome in a 15 M_sun type II SN if rotational mixing and/or preferential trapping of N from 15N-rich regions in the ejecta is considered. The isotopic characteristics of C, N, Si and initial 26Al/27Al ratios in small X grains are remarkably similar to those of large X grains (2-10 ?m). Titanium-44 concentrations are generally much higher in smaller grains, indicative of the presence of Ti-bearing subgrains that might have served as condensation nuclei for silicon carbide. The fraction of X grains among presolar silicon carbide is largely independent of grain size. This implies similar grain size distributions for silicon carbide from carbon stars (mainstream grains) and supernovae (X grains), a surprising conclusion in view of the different conditions for dust formation in these two types of stellar sources.

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