Other
Scientific paper
Jun 2010
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confeti14t&link_type=abstract
"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec
Other
Theory
Scientific paper
The recoupled pair bonding model and high level ab initio calculations [MRCI, RCCSD(T)] with correlation consistent basis sets were used to examine the optimized structures, bonding behavior and bond energies of bound HSO, SOH, OSF and SOF doublet and quartet states. This was done by the systematic addition of H or F to the 3Σ-, 1Δ and 3Π states of SO or by adding O(3P,1D) to the 2Π and 4Σ- states of SF. Of particular interest are those states that are either formed as a result of decoupling a pair of electrons or by further addition to a molecule that has already undergone the decoupling process. One of the goals of these studies is to explore the effect of ligand properties such as electronegativity or electron affinity in order to anticipate their impact on trends in bond energy and other properties similar to those observed in previous SFn (n=1--6) recoupled pair bonding studies. This study marks the first exploration of the behavior of a divalent ligand in hypervalent bonding under the recoupled pair bonding model.
Dunning Thom H. Jr.
Takeshita Tyler Y.
Woon David E.
No associations
LandOfFree
Application of the Recoupled Pair Bonding Model to Bound Doublet and Quartet States of Hso, Soh, Osf and Sof does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Application of the Recoupled Pair Bonding Model to Bound Doublet and Quartet States of Hso, Soh, Osf and Sof, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Application of the Recoupled Pair Bonding Model to Bound Doublet and Quartet States of Hso, Soh, Osf and Sof will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-1593908